From my limited experience along with web and YouTube searches, the DTMF codes allow a user to access devices using the radio. This can include repeaters, garage doors, and anything else where your radio might be used as a remote with a particular configured device. I have not use for this function and dont want to make my radios open to receiving unwanted codes.
The Kill/Stun function is an anti-theft function. Government agencies have this built into their public safety equipment. Depending on how much one spends for a mobile or HT, I can understand how you may want to brick the device if it was stolen. Getting it back would be another issue.
I think if you change the default code in CHIRP or CPS software it should limit someone from using a factory code to mess with your radio.