Not the entire range. The FCC has identified four sets of specific channels. 30 in all on frequencies in the 462 MHz range and the 467 MHz range. 463-466 MHz are not GMRS. We stay to those channels and we don’t get to twist our VFO knob and pick a clear frequency wherever we want.
Channels 15-22 are used for simplex communications, where people transmit directly to each other, taking turn transmitting and receiving on a single frequency.
If you add exactly 5 MHz to each of the 15-22 channels, you get the frequencies used for channels 23-30. So, 462.550 MHz becomes 467.550 MHz.
Channels 23-30 are used to transmit to a repeater. Generally speaking that’s almost the only traffic on these channels: to the repeater. Then, the repeater generally transmits on the corresponding channel in the 15-22 range. So, channels 15-22 are shared between simplex communications and transmissions from repeaters. The fact that these are shared and limited to these eight channels is one of the shortcomings of GMRS.