As @OffRoaderX indicated, starting out with ham radios is going to make it a little more difficult. I have some UV-5Rs and an AT-778UV so if you have any specific questions about those I may be able to help. The way tones work is the same across the board. Here is a few very basic pointers to hopefully help you get going:
Simplex: radio to radio
Duplex: radio to repeater (offset)
GMRS offset is +5MHz. GMRS radios should already have this set on the repeater channels for you. Ham radios don't so you have to set it yourself.
When using a repeater, RX will be a frequency 462.### and TX will be a frequency of 467.### with the same .###. See note above.
Tones:
Most repeaters use a "tone" on the RX or "input" of the repeater which will be the 467.### frequency.
These tones are sometimes called PL or DPL tones, CTCSS, etc. but they work the same.
When a repeater, or radio has a tone set on the RX, it will squelch out (ignore) any signal that does not carry that same tone. Therefore, you must use the same tone on your TX that the repeater uses on it's RX.
You do not have to use a tone on your RX. Without any tone on RX, you will hear all signals in that frequency.
Hope this helps.