Out of the box, using the alternative CPS programming software provided with the radio, CPEditor by MM7DBT, it transmits and receives on the GMRS channels; well at least the couple of repeaters channels that I have used it on. I can't imagine that if it works randomly on those, it would not work on all of them. Of course avoid transmitting on Channels 8-14, as this radio probably exceeds 1/2 watt on Low.
I just acquired a hotspot and this is an extremely versatile technology. It was setup for me to access both the Brandmeister and TGIF Networks and I only have experience on Brandmeister. You just go to the Brandmeister Hoseline and can see all of the activity that is currently available and can listen to each channel by simply clicking on it. Then by clicking on Player, you can easily see which Callsigns are using that channel and can easily disconnect from that channel, too.
Once you get familiar with activity patterns, you can add these channels to your codeplug and listen to them from the radio.
A good channel to start with is World (91). Just sit back and hear all those Hams around the world easily talking to each other.
Not something that the "old-timers" would accept as DX, but in the modern world it is another tool in the Ham Radio toolbox for those who want to use it.